منابع مشابه
Selected overtone mobility spectrometry.
A new means of acquiring overtone mobility spectrometry (OMS) data sets that allows distributions of ions for a prescribed overtone number is described. In this approach, the drift fields applied to specific OMS drift regions are varied to make it possible to select different ions from a specific overtone that is resonant over a range of applied frequencies. This is accomplished by applying dif...
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متن کاملGridless overtone mobility spectrometry.
A novel overtone mobility spectrometry (OMS) instrument utilizing a gridless elimination mechanism and cooperative radio frequency confinement is described. The gridless elimination region uses a set of mobility-discriminating radial electric fields that are designed so that the frequency of field application results in selective transmission and elimination of ions. To neutralize ions with mob...
متن کاملOvertone mobility spectrometry: part 5. Simulations and analytical expressions describing overtone limits.
Mathematical expressions for the analytical duty cycle associated with different overtones in overtone mobility spectrometry are derived from the widths of the transmitted packets of ions under different instrumental operating conditions. Support for these derivations is provided through ion trajectory simulations. The outcome of the theory and simulations indicates that under all operating con...
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ژورنال
عنوان ژورنال: Nature
سال: 1875
ISSN: 0028-0836,1476-4687
DOI: 10.1038/012475a0